Dalton transactions (Cambridge, England : 2003), (31)(31), 6120-6126 (2010-05-08)
A new family of flexible scorpionate ligands based on 2-mercaptopyridine is reported. The tris- and bis-substituted ligands, K[HB(mp)(3)] (1) and Na[H(2)B(mp)(2)] (2) (mp = 2-mercaptopyridine) have been prepared and fully characterised. The structural characterisation of 1 reveals an unprecedented mu(3)-kappa(3)-SS'H-eta(1)eta(1)eta(2)-kappa(2)-S''C-eta(1)eta(1)-kappa(1)-S'-eta(1)
Terpyridineplatinum(II) complexes (TPCs) efficiently inhibit the proliferation of glioblastoma cells in vitro and have been tested successfully in a rodent glioblastoma model. Apart from intercalation with DNA, the major mechanism of action of TPCs is a very potent and specific
Physical chemistry chemical physics : PCCP, 11(34), 7469-7475 (2009-08-20)
The engineering of cavity void metallic arrays allows to vary the plasmon-polariton mode energies from the near infrared to the ultraviolet through the tuning of the void height and diameter, and the selection of the appropriate material. Typically Au nanocavity
The synthesis of new 4- and 5-substituted-3-cyanopyridine nucleosides has been performed by reacting the silylated pyridines and penta-omicron-acetyl-alpha -D-glycopyranose in dichloroethane in the presence of SnCl4. The free nucleosides were tested for their potential activity against HIV and different types
In this present study, the biocorrosion behaviour of Bacillus thuringiensis EN2 and B. oleronius EN9 on copper metal CW024A (Cu) in cooling water system (1% chloride) were evaluated using weight loss, electrochemical impedance spectroscopy (EIS) and surface analysis. In presence of
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