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10460-U

Supelco

Carbotrap® Adsorbent

matrix Carbotrap® Y, 20-40 mesh, bottle of 10 g

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About This Item

EC Number:
UNSPSC Code:
23201100
NACRES:
SB.54

product line

Carbotrap®

form

granular

packaging

bottle of 10 g

technique(s)

LPLC: suitable

surface area

~24 m2/g

matrix

Carbotrap® Y

matrix active group

carbon

particle size

20-40 mesh

pore size

~0 cm3/g macroporosity
~0 cm3/g mesoporosity
~0 cm3/g microporosity
~0 Å pore diameter

density

~0.44 g/mL (free fall density)

separation technique

reversed phase

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General description

A graphitized carbon black (GCB) can be non-porous or porous. The graphitization process results in a highly pure surface with great adsorption and desorption (if required) properties. Surface interactions depend solely on dispersion (London) forces. These particles are:
  • Granular
  • Friable
  • Used for molecules with an analyte size relative to C3-C20+ n-alkanes
  • Hydrophobic (can be used in high humidity environments)

Generally, GCB adsorbents offer weaker relative adsorptive strength compared to carbon molecular sieve (CMS) adsorbents, and similar relative adsorptive strength compared to spherical graphitized polymer carbon (SGPC) adsorbents. Our Carbotrap products are a type of GCB adsorbent.
  • Particles are 20/40 mesh
  • These large particles allow high flow rates without excessive pressure drops

For more information about any of our specialty carbon adsorbents, please visit sigma-aldrich.com/carbon
Carbopack Y was used for determination of contamination caused by pesticides like alachlor, atrazine, captan, formothion, lindane and phosalone in atmospheric samples.[1] Carbopack Y was modified with mono-molecular layer of heptakis-(2,3,6-tri-O-methyl)-ß-cyclodextrin and was used in gas chromatography to study the effect of size and spatial structure of adsorbate molecules on adsorption of organic vapours.[2]
Carbotrap®/Carbopack adsorbent can withstand high bake-out temperature without losing the mechanical and chemical integrity. It has a high affinity for isoprene and does not retain significant amounts of water. Furthermore it has a tendency to pulverize if it is packed too tightly.[3] Carbotrap®/Carbopack adsorbent was used to quantitatively determine trace amounts of volatile organic compounds (VOCs) in air.[4] It was also used for designing sampling protocols on the basis of its retention volume of the gaseous organic compounds of interest.[5]

Legal Information

Carbopack is a trademark of Merck KGaA, Darmstadt, Germany
Carbotrap is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class

11 - Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Adsorption/thermal desorption-GC/MS for the analysis of pesticides in the atmosphere.
Clement M, et al.
Chemosphere, 40 (1), 49-56 (2009)
Adsorption of organic vapors on the Carbopack Y carbon adsorbent modified with heptakis-(2, 3, 6-tri-O-methyl)-?-cyclodextrin.
Kudryashov SY, et al.
Russian Journal of Physical Chemistry A, 84 (3), 495-502 (2010)
Gas phase retention volume behavior of organic compounds on Carbotrap graphitized carbon.
Pankow JF.
Journal of Chromatography A, 547, 488-493 (1991)
Plant Volatile Analysis.
Linskens HF and Jackson JF.
Modern Methods of Plant Analysis, 19, 54-56 (1997)
Comparison of Tenax TA and Carbotrap for sampling and analysis of volatile organic compounds in air.
Rothweiler H, et al.
Atmospheric Environment, 25 (2), 231-235 (1991)

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Synthetic CMS carbons offer tailored adsorbents for specific applications.

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