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T8156

Sigma-Aldrich

Adrenorphin

≥95% (HPLC)

Synonym(s):

Metorphamide, Tyr-Gly-Gly-Phe-Met-Arg-Arg-Val

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About This Item

Empirical Formula (Hill Notation):
C44H68N14O10S
CAS Number:
88866-92-6
Molecular Weight:
985.16
MDL number:
MFCD00076434
UNSPSC Code:
12352200
PubChem Substance ID:
329826875
NACRES:
NA.26
assay:
≥95% (HPLC)

assay

≥95% (HPLC)

storage temp.

−20°C

SMILES string

CSCC[C@H](NC(=O)[C@H](Cc1ccccc1)NC(=O)CNC(=O)CNC(=O)[C@@H](N)Cc2ccc(O)cc2)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](C(C)C)C(O)=O

InChI

1S/C44H68N14O10S/c1-25(2)36(42(67)68)58-40(65)31(12-8-19-51-44(48)49)56-38(63)30(11-7-18-50-43(46)47)55-39(64)32(17-20-69-3)57-41(66)33(22-26-9-5-4-6-10-26)54-35(61)24-52-34(60)23-53-37(62)29(45)21-27-13-15-28(59)16-14-27/h4-6,9-10,13-16,25,29-33,36,59H,7-8,11-12,17-24,45H2,1-3H3,(H,52,60)(H,53,62)(H,54,61)(H,55,64)(H,56,63)(H,57,66)(H,58,65)(H,67,68)(H4,46,47,50)(H4,48,49,51)/t29-,30-,31-,32-,33-,36-/m0/s1

InChI key

ZBRXWGQCHSFAHM-MWSMAVIUSA-N

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
079F05221
050H0638
050H06382

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S J Bunn et al.
Biochemical pharmacology, 41(5), 715-722 (1991-03-01)
The ability of a number of opioid agonists and antagonists to affect nicotine-induced 45Ca2(+)-uptake into cultured bovine adrenal medullary cells has been investigated. High (10 microM) concentrations of the opioid agonist bremazocine produced a significant inhibition of nicotine-induced 45Ca2(+)-uptake throughout
Vadivel Ganapathy et al.
The AAPS journal, 7(4), E852-E856 (2006-04-06)
Transmembrane transport of endogenous as well as synthetic opioid peptides is a critical determinant of pharmacokinetics and biologic efficacy of these peptides. This transport process influences the distribution of opioid peptides across the blood-brain barrier and their elimination from the
T Yanase et al.
The Journal of clinical endocrinology and metabolism, 64(4), 692-697 (1987-04-01)
We studied the secretion and tissue contents of adrenorphin in human pheochromocytomas. In 17 human pheochromocytomas from 11 patients, we found a remarkably wide distribution in immunoreactive adrenorphin levels (3-7771 pg/mg tissue). Adrenomedullary pheochromocytomas contained a significantly larger amount of
P D Marley et al.
Brain research, 363(1), 10-17 (1986-01-15)
Opioid peptides are found in high concentrations in the adrenal medulla. Recently, a novel opioid octapeptide, metorphamide, possessing an amidated C-terminal, was characterized and also found to be present in adrenal tissue. We have studied the ability of this novel
Fuyu Guan et al.
Analytica chimica acta, 985, 79-90 (2017-09-03)
The ability to analyze biological samples for multitudinous exogenous peptides with a single analytical method is desired for doping control in horse racing. The key to achieving this goal is the capability of extracting all target peptides from the sample
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