T24007
Tetramethylsilane
ACS reagent, NMR grade, ≥99.9%
Synonym(s):
TMS
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25 G
$58.10
100 G
$174.00
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25 G
$58.10
100 G
$174.00
About This Item
Linear Formula:
Si(CH3)4
CAS Number:
Molecular Weight:
88.22
Beilstein/REAXYS Number:
1696908
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
grade:
ACS reagent
assay:
≥99.9%
technique(s):
NMR: suitable
bp:
26-28 °C (lit.)
vapor pressure:
11.66 psi ( 20 °C)
Recommended Products
grade
ACS reagent
Quality Level
vapor pressure
11.66 psi ( 20 °C)
assay
≥99.9%
form
liquid
autoignition temp.
842 °F
expl. lim.
0.34-6.3 %
technique(s)
NMR: suitable
evapn. residue
≤0.05%
refractive index
n20/D 1.358 (lit.)
bp
26-28 °C (lit.)
mp
−99 °C (lit.)
density
0.648 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C[Si](C)(C)C
InChI
1S/C4H12Si/c1-5(2,3)4/h1-4H3
InChI key
CZDYPVPMEAXLPK-UHFFFAOYSA-N
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application
Tetramethylsilane can be used as:
- A precursor to synthesize α-SiC by chemical vapor deposition[1].
- A reactant to synthesize 1,3,5,7-tetramethyladamantane from adamantane in the presence of aluminum chloride and dichloromethane[2].
- A solvent for the hydroaminomethylation of 1-octene with morpholine[3].
- A methylating reagent for the conversion of germanium tetrachloride to tetramethylgermanium, trimethylgermanium chloride, dimethylgermanium dichloride or methylgermanium trichloride[4].
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 1
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
-16.6 °F - closed cup
flash_point_c
-27 °C - closed cup
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Tetramethylsilane in synthesis: selective mono-and polymethylations of germanium tetrachloride
Bordeau M, et al.
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