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61200

Sigma-Aldrich

Copper(II) oxide

puriss. p.a., ≥99.0% (RT), powder

Synonym(s):

Cupric oxide

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About This Item

Empirical Formula (Hill Notation):
CuO
CAS Number:
Molecular Weight:
79.55
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:

grade

puriss. p.a.

assay

≥99.0% (RT)

form

powder

impurities

≤0.002% total nitrogen (N)
≤0.02% insoluble matter in HCl
≤0.05% total sulfur (as SO4)

anion traces

chloride (Cl-): ≤50 mg/kg

cation traces

Ca: ≤100 mg/kg
Cd: ≤10 mg/kg
Co: ≤10 mg/kg
Cr: ≤50 mg/kg
Fe: ≤500 mg/kg
K: ≤50 mg/kg
Mg: ≤100 mg/kg
Mn: ≤10 mg/kg
Na: ≤500 mg/kg
Ni: ≤50 mg/kg
Pb: ≤500 mg/kg
Zn: ≤100 mg/kg

SMILES string

[Cu]=O

InChI

1S/Cu.O

InChI key

QPLDLSVMHZLSFG-UHFFFAOYSA-N

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General description

Copper(II) oxide (Cupric oxide, CuO) contains copper in the +2 valence state. A refinement of its crystal structure has been described by single crystal X-ray diffraction studies.[1] CuO is useful for the fabrication of solid state gas sensors.[2] It can be synthesized from copper oxalate.[3]

Application

Copper(II) oxide may be used in the preparation of imidazole[4] and single crystals of CuO.[1]

pictograms

Environment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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DSC kinetics of the thermal decomposition of copper (II) oxalate by isoconversional and maximum rate (peak) methods.
Muraleedharan K and Kripa S.
Journal of Thermal Analysis and Calorimetry, 115(2), 1969-1978 (2014)
A refinement of the crystal structure of copper (II) oxide with a discussion of some exceptional esd's.
?sbrink S and Norrby LJ.
Acta Crystallographica Section B, Structural Science, 26(1), 8-15 (1970)
Eagleson M.
Concise Encyclopedia Chemistry, 523-523 (1994)
Copper (II) oxide nanowires for p-type conductometric NH3 sensing.
Shao F, et al.
Applied Surface Science, 311, 177-181 (2014)
Sumanta Kumar Meher et al.
Nanoscale, 5(5), 2089-2099 (2013-02-06)
In the quest to enhance the selectivity and sensitivity of novel structured metal oxides for electrochemical non-enzymatic sensing of glucose, we report here a green synthesis of unique sandwich-structured CuO on a large scale under microwave mediated homogeneous precipitation conditions.

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