Thin films of ammonium iodide were studied by far IR spectra from −170°C to room temperature. Laser excited Raman spectra of polycrystalline NH4I was also recorded.[1]
Application
Ammonium iodide (NH4I) may be used in the following studies:
Cyanation protocol of aryl boronic acids, boronates and borate salts. It has a dual role in the protocol to provide iodide and nitrogen atom of the cyano moiety.[2]
Chemical communications (Cambridge, England), 51(1), 210-212 (2014-11-20)
A novel ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones is described. The process proceeded smoothly under metal-free conditions with high stereoselectivity and good functional group tolerance. The reaction mechanism was revealed
Low-Frequency Vibrations in Ammonium Iodide and Ammonium Bromide.
Journal of the American Chemical Society, 134(5), 2528-2531 (2012-01-28)
The cyanation of aromatic boronic acids, boronate esters, and borate salts was developed under copper-mediated oxidative conditions using ammonium iodide and DMF as the source of nitrogen and carbon atom of the cyano unit, respectively. The procedure was successfully extended
A novel approach using wavelength dispersive X-ray fluorescence (WDXRF) spectrometry combined with an activated carbon (AC) disk was developed for the determination of total iodine concentrations in water samples. Dissolved iodine species (i.e., I(-) and IO3(-)) in water samples were
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