905151
(±)-cis-4-fluorocyclohexylboronic acid pinacol ester
≥95% (sum of diastereomers)
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About This Item
Empirical Formula (Hill Notation):
C12H22BFO2
CAS Number:
Molecular Weight:
228.11
UNSPSC Code:
12352101
description
Diastereomer Ratio: > 8:1
assay
≥95% (sum of diastereomers)
form
liquid
storage temp.
2-8°C
Application
The incorporation of fluorine in agrochemical and pharmaceutical compounds is of high interest due to the ability to fine-tune the polarity, pKA-value, conformation and metabolic stability. Derived from a cis-selective hydrogenation developed by Glorius and coworkers, this boronic ester can be used in various organometallic transformations.
Storage Class
10 - Combustible liquids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Mario P Wiesenfeldt et al.
Science (New York, N.Y.), 357(6354), 908-912 (2017-08-12)
All-cis-multifluorinated cycloalkanes exhibit intriguing electronic properties. In particular, they display extremely high dipole moments perpendicular to the aliphatic ring, making them highly desired motifs in material science. Very few such motifs have been prepared, as their syntheses require multistep sequences
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