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86879

Supelco

Tetrabutylammonium hexafluorophosphate

for electrochemical analysis, ≥99.0%

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25 G
$178.00
100 G
$652.00

$178.00

Available to ship onApril 29, 2025Details

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25 G
$178.00
100 G
$652.00

About This Item

Linear Formula:
(CH3CH2CH2CH2)4N(PF6)
CAS Number:
3109-63-5
Molecular Weight:
387.43
Beilstein/REAXYS Number:
4056584
EC Number:
221-472-6
MDL number:
MFCD00011748
UNSPSC Code:
26111700
PubChem Substance ID:
329769335
NACRES:
NB.61

$178.00

Available to ship onApril 29, 2025Details

Request a Bulk Order

Quality Level

100

assay

≥99.0% (CHN)
≥99.0%

form

solid

mp

244-246 °C (lit.)

solubility

acetonitrile: 0.1 g/mL, clear, colorless

SMILES string

F[P-](F)(F)(F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1

InChI key

BKBKEFQIOUYLBC-UHFFFAOYSA-N

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General description

Tetrabutylammonium hexafluorophosphate (TBAHFP) is a quaternary ammonium salt, mainly used as electrolyte. It is soluble in solvents like liquid sulphur dioxide and methylene chloride.
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Application

TBAHFP has been used in the preparation of poly-3-methylthiophene combined with γ-cyclodextrin (P3MT/γ-CD) electrode using electrochemical synthesis method.[1]

Other Notes

Supporting electrolyte soluble in organic solvents which is very stable[2]

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM8532
BCCL1097
BCCK6470
BCCH7900
BCCG7830

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A novel electrochemical synthesis of poly-3-methylthiophene-gamma-cyclodextrin film Application for the analysis of chlorpromazine and some neurotransmitters.
Bouchta D
Biosensors And Bioelectronics, 20(11), 2228-2235 (2005)
M.M. Baizer
Organic Electrochemistry null
Md Khairul Hoque et al.
Frontiers in chemistry, 8, 593932-593932 (2020-11-27)
Nitrogen-free amorphous carbon thin films prepared via sputtering followed by graphitization, were used as precursor materials for the creation of N-doped carbon electrodes with varying degrees of amorphization. Incorporation of N-sites was achieved via nitrogen plasma treatments which resulted in
Ting-Ting Li et al.
ChemSusChem, 12(11), 2402-2408 (2019-05-10)
A RuII complex [Ru(PO3 Et2 -ph-tpy)(6-mbpy)(NCCH3 )]2+ [PO3 Et2 -ph-tpy=diethyl(4-[(2,2':6',2''-terpyridin)-4'-yl]phenyl)phosphonate; 6-mbpy=6-methyl-2,2'-bipyridine] is explored as a molecular catalyst for electrocatalytic CO2 reduction in both a homogeneous solution and, as a phosphonated derivative, on nanocrystalline-TiO2 surfaces. In CH3 CN, the complex acts
Sonia Bruña et al.
Dalton transactions (Cambridge, England : 2003), 43(35), 13187-13195 (2014-07-17)
Reaction of Fe3(CO)12 with 1,2-dithiolene HSC6H2Cl2SH affords a mixture of complexes [Fe2(CO)6(μ-SC6H2Cl2S)] 1, [Fe2(SC6H2Cl2S)4] 2 and [Fe3(CO)7(μ3-SC6H2Cl2S)2] 3. In the course of the reaction the trimetallic cluster 3 is first formed and then converted into the known dinuclear compound 1
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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. I would like to use this product into the glovebox. I didn't open the bottle yet but, as the package does not have the legend ARGON SEALED, I do not know if I can put in directly into the glovebox or how can I proceed (dry in vacuum oven, for example).

    1 answer

    1. This product is not packaged under an inert gas, such as argon or nitrogen. The most common practice when using this type of material in a glove box environment is to transfer a smaller amount of the reagent to a vial or flask and dry it under a vacuum, prior to introducing the glovebox.

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