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60244

Supelco

Potassium fluoride on aluminum oxide

extent of labeling: ~5.5 mmol/g F- loading

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About This Item

Linear Formula:
KF-Al2O3
Beilstein/REAXYS Number:
3902818
MDL number:
UNSPSC Code:
23151817
PubChem Substance ID:
NACRES:
NA.22

extent of labeling

~5.5 mmol/g F- loading

SMILES string

[F-].[K+]

InChI

1S/FH.K/h1H;/q;+1/p-1

InChI key

NROKBHXJSPEDAR-UHFFFAOYSA-M

Other Notes

Supported fluoride, useful as catalyst and supported base for elimination, addition and condensation reactions [1][2]; Potassium fluoride on aluminum oxide was shown by L. Weinstock et al. to be in reality KOH and K3AlF6 on aluminum oxide[3]

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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L. Weinstock et al.
Tetrahedron Letters, 27, 3845-3845 (1986)
F. Texier-Boullet et al.
Tetrahedron, 41, 1259-1259 (1985)
J.H. Clark et al.
Journal of the Chemical Society. Perkin Transactions 1, 2253-2253 (1983)
Elena Chiurchiù et al.
Molecules (Basel, Switzerland), 24(24) (2019-12-19)
Highly functionalized furans are the key scaffolds of many pharmaceuticals and bioactive natural products. Herein, we disclose a new fruitful synthesis of polyfunctionalized furans starting from β-nitroenones and α-functionalized ketones. The protocol involves two steps promoted by solid supported species
Deniz Ekinci et al.
Bioorganic & medicinal chemistry, 19(2), 744-748 (2011-01-08)
Carbonic anhydrase (CA; EC 4.2.1.1) was purified from the gill of the teleost fish Dicentrarchus labrax (European seabass). The purification procedure consisted of a single step affinity chromatography on Sepharose 4B-tyrosine-sulfanilamide. The enzyme was purified 84.9-fold with a yield of

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