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34120

Supelco

BDE No 209 solution

50 μg/mL in isooctane:toluene (9:1), analytical standard

Synonym(s):

Decabromodiphenyl ether solution, Decabromodiphenyl oxide

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About This Item

Empirical Formula (Hill Notation):
C12Br10O
CAS Number:
1163-19-5
Molecular Weight:
959.17
MDL number:
MFCD00000059
UNSPSC Code:
41116107
PubChem Substance ID:
329754827
NACRES:
NA.24

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

concentration

50 μg/mL in isooctane:toluene (9:1)

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

environmental

format

single component solution

storage temp.

2-8°C

SMILES string

Brc1c(Br)c(Br)c(Oc2c(Br)c(Br)c(Br)c(Br)c2Br)c(Br)c1Br

InChI

1S/C12Br10O/c13-1-3(15)7(19)11(8(20)4(1)16)23-12-9(21)5(17)2(14)6(18)10(12)22

InChI key

WHHGLZMJPXIBIX-UHFFFAOYSA-N

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General description

BDE No 209 is one of the congeners of polybrominated diphenyl ethers (PBDEs) which is extensively used in a number of consumer goods.

application

BDE No 209 may be used as a reference standard for the determination of BDE No 209 in:
  • House dust samples by liquid chromatography with negative-ion atmospheric pressure photoionization tandem mass spectrometry (LC/NI-APPI/MS/MS).
  • Sediment samples by selective pressurized liquid extraction (SPLE) followed by analysis using gas chromatography (GC) combined with negative chemical ionization (NCI)−MS in selective ion monitoring (SIM) mode.
  • Sewage sludge by GC-SIM with low resolution MS and in blood, muscle as well as liver samples of European starlings (Sturnus vulgaris) by GC-MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

target_organs

Central nervous system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

10.4 °F - closed cup

flash_point_c

-12 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCB3209
BCBW5352
BCBT4344
BCBR7868V

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NIST2257

PBDE congeners in 2,2,4-trimethylpentane

Development of quantitative structure gas chromatographic relative retention time models on seven stationary phases for 209 polybrominated diphenyl ether congeners
Wang W, et al.
Journal of Chromatography A, 1103(2), 314-328 (2006)
Polybrominated diphenyl ether in sewage sludge in Germany
Knoth W, et al.
Chemosphere, 67(9), 1831-1837 (2007)
Chunyan Sun et al.
Chemosphere, 89(4), 420-425 (2012-06-15)
There have been serious concerns about polybromodiphenyl ethers (PBDEs) in the environment because of their global distribution and bioaccumulation. Owing to strong hydrophobicity of PBDEs, the regular photocatalytic system, in which the substrate is solvated in the bulk solution, is
Kai Yu et al.
Environmental science & technology, 46(16), 8969-8975 (2012-08-01)
Subnanoscale zerovalent iron (ZVI) synthesized using smectite clay as a template was utilized to investigate reduction of decabromodiphenyl ether (DBDE). The results revealed that DBDE was rapidly debrominated by the prepared smectite-templated ZVI with a reaction rate 10 times greater
Jing Wang et al.
Chemosphere, 89(7), 844-849 (2012-06-05)
The photolytic degradation of decabromodiphenyl ethane (DBDPE), an alternative flame retardant to decabromodiphenyl ether, was investigated in a variety of matrixes (n-hexane, tetrahydrofuran, methanol/water, humic acid/water, and silica gel) by irradiation under ultraviolet light and in n-hexane under natural light.
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