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00852

Sigma-Aldrich

(R)-mono-Ethyl 3-acetoxyglutarate

≥97.0% (T)

Synonym(s):

(R)-Monoethyl 3-acetoxyglutarate

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About This Item

Empirical Formula (Hill Notation):
C9H14O6
CAS Number:
Molecular Weight:
218.20
Beilstein/REAXYS Number:
5518295
MDL number:
UNSPSC Code:
12352202
PubChem Substance ID:
NACRES:
NA.22

assay

≥97.0% (T)

optical activity

[α]20/D +7.2±0.5°, c = 1% in chloroform

optical purity

enantiomeric ratio: ≥98:2 (NMR)

refractive index

n20/D 1.445

density

1.190 g/mL at 20 °C (lit.)

storage temp.

2-8°C

SMILES string

CCOC(=O)C[C@@H](CC(O)=O)OC(C)=O

InChI

1S/C9H14O6/c1-3-14-9(13)5-7(4-8(11)12)15-6(2)10/h7H,3-5H2,1-2H3,(H,11,12)/t7-/m1/s1

InChI key

XTDRHYRKEIVYIN-SSDOTTSWSA-N

Other Notes

Chiral building block[1][2][3][4]

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves


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A.S. Gopalan et al.
Tetrahedron Letters, 25, 5235-5235 (1984)
D.W. Brooks et al.
The Journal of Organic Chemistry, 52, 192-192 (1987)
T. Rosen et al.
Tetrahedron, 42, 4909-4909 (1986)
D.W. Brooks et al.
Tetrahedron Letters, 24, 3059-3059 (1983)

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