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I7632

Iodobenzene

98%

Synonym(s):

1-Iodobenzene, 4-Iodobenzene, Benzene iodide, Phenyl iodide

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Pack SizeSKUAvailabilityPrice
5 g

Available to ship TODAYfromMILWAUKEE

$40.30
100 g

Available to ship TODAYfromMILWAUKEE

$87.60
500 g

Available to ship TODAYfromMILWAUKEE

$279.00

About This Item

Empirical Formula (Hill Notation):
C6H5I
CAS Number:
Molecular Weight:
204.01
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-719-6
Beilstein/REAXYS Number:
1446140
MDL number:
Assay:
98%

$40.30


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Quality Level

assay

98%

refractive index

n20/D 1.62 (lit.)

bp

188 °C (lit.)

mp

−29 °C (lit.)

density

1.823 g/mL at 25 °C (lit.)

SMILES string

Ic1ccccc1

InChI

1S/C6H5I/c7-6-4-2-1-3-5-6/h1-5H

InChI key

SNHMUERNLJLMHN-UHFFFAOYSA-N

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1 of 1

This Item
394602662283603732
assay

98%

assay

99% (CP)

assay

97%

assay

99% (CP)

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

-

refractive index

n20/D 1.62 (lit.)

refractive index

n20/D 1.6161 (lit.)

refractive index

-

refractive index

-

density

1.823 g/mL at 25 °C (lit.)

density

1.868 g/mL at 25 °C

density

-

density

1.876 g/mL at 25 °C

bp

188 °C (lit.)

bp

188 °C (lit.)

bp

-

bp

188 °C (lit.)

mp

−29 °C (lit.)

mp

-29 °C (lit.)

mp

104-109 °C

mp

-29 °C (lit.)

General description

Iodobenzene, also known as phenyl iodide, is commonly used as an arylating agent in various cross-coupling reactions.[1][2][3]

Application

Iodobenzene is used in various C-C coupling reactions. It can be used in the preparation of iodobenzene dichloride, which is employed as an oxidant to oxidize alcohols to carbonyl compounds and as a chlorinating agent.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

170.6 °F - closed cup

flash_point_c

77 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Heck reactions of iodobenzene and methyl acrylate with conventional supported palladium catalysts in the presence of organic and/and inorganic bases without ligands.
Zhao, Fengyu et al.
Chemistry?A European Journal , 6(5), 843-848 (2000)
Ring-Opening 1, 3-Dichlorination of Donor-Acceptor Cyclopropanes by Iodobenzene Dichloride.
Garve, Lennart KB et al.
Organic Letters, 16(21), 5804-5807 (2014)
Iodobenzene dichloride as a stoichiometric oxidant for the conversion of alcohols into carbonyl compounds; two facile methods for its preparation.
Zhao, Xue-Fei and Zhang, Chi
Synthesis, 2007(04), 551-557 (2007)
Size effects of PVP- Pd nanoparticles on the catalytic Suzuki reactions in aqueous solution.
Li, Yin et al.
Langmuir, 18(12), 4921-4925 (2002)
Minfeng Zeng et al.
The Journal of organic chemistry, 75(8), 2556-2563 (2010-03-23)
Palladium-catalyzed reductive homocoupling of aromatic halides can be performed in alcohol solutions without any auxiliary reducing reagents. Pd(dppf)Cl(2) [dppf = 1,1'-bis(diphenylphosphino)ferrocene] has been shown as the most effective catalyst among the palladium catalysts screened for the model reductive homocoupling of

Articles

Our strategy is to synthesize mesoporous carbonaceous materials (“Starbons”) using mesoporous expanded starch as the precursor without the need for a templating agent.

Global Trade Item Number

SKUGTIN
I7632-100G-A04061833858301
I7632-5G-A04061833858318
I7632-500G-A04061832677064

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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