ALD00456

Sodium N-benzyloxycarbonyl-4-piperidinesulfinate

• Empirical Formula (Hill Notation): C₁₃H₁₆NNaO₄S
• Molecular Weight: 305.33
• UNSPSC Code: 12352005
• PubChem Substance ID: 329772685
• NACRES: NA.22

Properties

• form: powder
• reaction suitability: reaction type: C-C Bond Formation; reaction type: C-H Activation; reagent type: catalyst
• SMILES string: O=S(O[Na])C1CCN(C(OCC2=CC=CC=C2)=O)CC1
• InChI: 1S/C13H17NO4S.Na/c15-13(18-10-11-4-2-1-3-5-11)14-8-6-12(7-9-14)19(16)17;/h1-5,12H,6-10H2,(H,16,17);/q;+1/p-1
• InChI key: LCXWFQBBQAGBHZ-UHFFFAOYSA-M

Description

General description

Sodium N-benzyloxycarbonyl-4-piperidinesulfinate is a sulfinate reagent bearing an N-substituted piperidine moiety.

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Other Notes

Radical-Based Regioselective C–H Functionalization of Electron-Deficient Heteroarenes: Scope, Tunability, and Predictability

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable