ALD00022

Diethyl 2-((1-(2-oxo-2-phenylethyl)-1H-pyrrol-2-yl)methylene)malonate

97%

• Empirical Formula (Hill Notation): C₂₀H₂₁NO₅
• CAS Number: 1508247-00-4
• Molecular Weight: 355.38
• UNSPSC Code: 12352100
• PubChem Substance ID: 329772522
• NACRES: NA.22

Properties

• assay: 97%
• form: powder
• mp: 118 °C
• storage temp.: 2-8°C
• SMILES string: O=C(CN1C(C=C(C(OCC)=O)C(OCC)=O)=CC=C1)C2=CC=CC=C2
• InChI: 1S/C20H21NO5/c1-3-25-19(23)17(20(24)26-4-2)13-16-11-8-12-21(16)14-18(22)15-9-6-5-7-10-15/h5-13H,3-4,14H2,1-2H3
• InChI key: JMNYUFCXEYSRIE-UHFFFAOYSA-N

Description

Application

Building block is employed in the enantioselective synthesis of 5, 6-dihydroindolizines through a cascade sequence initiated by (S)-(–)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether (Aldrich 677183).

Other Notes

Core-Structure-Motivated Design of Iminium–Enolate Organocascade Reactions: Enantioselective Syntheses of 5, 6-Dihydroindolizines

Safety Information

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable