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912646

Sigma-Aldrich

tBuBrettPhos Pd G6 bromide

Synonym(s):

tBuBrettPhos OAC precatalyst Br

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100 MG
$169.00
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$1,230.00

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100 MG
$169.00
1 G
$1,230.00

About This Item

Empirical Formula (Hill Notation):
C38H53BrF3O2PPd
Molecular Weight:
816.12
UNSPSC Code:
12161600
NACRES:
NA.22

$169.00

Available to ship onMay 05, 2025Details

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form

powder or crystals

Quality Level

100

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Related Categories

Application

tBuBrettPhos Pd G6 bromide is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

Other Notes

Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands

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Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCL9587
SHBN8271

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Bryan T Ingoglia et al.
Organic letters, 19(11), 2853-2856 (2017-05-13)
In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts

Articles

Buchwald G6 Precatalysts: Oxidative Addition Complexes

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

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