901464

2,2′-Bi-1,3,2-dioxaborinane

≥95%

• Synonym(s): B₂(pro)₂, Propanediol diboron
• Empirical Formula (Hill Notation): C₆H₁₂B₂O₄
• CAS Number: 13826-25-0
• Molecular Weight: 169.78
• MDL number: MFCD08460171
• UNSPSC Code: 12352200
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: ≥95%
• form: powder or crystals
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 156 °C
• greener alternative category: Aligned,
• storage temp.: −20°C
• InChI: 1S/C6H12B2O4/c1-3-9-7(10-4-1)8-11-5-2-6-12-8/h1-6H2
• InChI key: FOGDFVUQHQEIPV-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced to increase catalytic efficiency. Click here for more information.

Application

As reported by the laboratory of James Morken, B₂(pro)₂ is an effective reagent for enantioselective diboration of alkenes when used in conjunction with the carbohydrate-derived catalysts TBS-DHG (901235) or DHR (901237). Useful for synthesis of other boron-containing molecules.

Other Notes

Carbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable