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900509

Sigma-Aldrich

Potassium 4-chloro-2-isonicotinyltrifluoroborate

≥95%

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About This Item

Empirical Formula (Hill Notation):
C6H3BClF3KNO
Molecular Weight:
247.45
UNSPSC Code:
12352200
PubChem Substance ID:
NACRES:
NA.22

assay

≥95%

form

powder or crystals

mp

237.2 °C

functional group

chloro

Application

Potassium acyltrifluroborates (KATs) are bench-, air-, and moisture-stable reagents for rapid chemoselective amide bond formations with hydroxylamines. These amide bond-forming reactions proceed under aqueous conditions without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Acylboranes: synthetic strategies and applications.
Scharnagl F K, et al.
Organic & Biomolecular Chemistry, 15(8), 1738-1752 (2017)

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Bode Group creates N-mesityl-NHC catalysts for enantioselective annulations and SnAP reagents for one-pot aldehyde conversion into N-heterocycles.

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