900348

Dicyclohexylamine borane

95%

• Synonym(s): DCAB, DICAB
• Empirical Formula (Hill Notation): C₁₂H₂₆BN
• CAS Number: 131765-96-3
• Molecular Weight: 195.15
• UNSPSC Code: 12352200
• PubChem Substance ID: 329769809
• NACRES: NA.22

Properties

• assay: 95%
• form: crystals
• reaction suitability: reagent type: reductant
• mp: 118.2 °C
• storage temp.: 2-8°C
• SMILES string: [H][N+](C1CCCCC1)([BH3-])C2CCCCC2
• InChI: 1S/C12H26BN/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12,14H,1-10H2,13H3
• InChI key: FWNIZOBKEDZMFC-UHFFFAOYSA-N

Description

Application

Dicyclohexylamine borane complex applied by the Pucheault Group at the Universite de Bordeaux as a cost effective and easy to handle alternative to current borylation reagents. In one pot, aryl and vinyl halides can be converted to the boronic acid derivative of your choice (BF₃K, Bpin, MIDA, and others) depending on quench and workup.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302,H315,H319
• pcodes: P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P332 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable