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Key Documents

83440

Sigma-Aldrich

Activated Nickel Catalyst

Synonym(s):

Nickel sponge

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About This Item

CAS Number:
MDL number:
UNSPSC Code:
12141729
PubChem Substance ID:

description

Application Test Activity ((Nitrobenzene hydrogenation) >= 22 ml/min*g)

Quality Level

assay

90-95% Ni basis (content, ICP)

form

suspension (water)

shelf life

limited shelf life, expiry date on the label

reaction suitability

core: nickel

SMILES string

[Ni]

InChI

1S/Ni

InChI key

PXHVJJICTQNCMI-UHFFFAOYSA-N

Application

Catalyst for homocoupling of halobenzenes; benzyl halide coupling; synthesis of β-hydroxynitriles; xylylene cycloadditions; synthesis of 3-arylpropanenitriles.

signalword

Danger

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Inaba, S.;Wehmeyer, R. M. et al.
The Journal of Organic Chemistry, 53, 339-339 (1988)
Inaba, S.; Rieke, R. D.
Tetrahedron Letters, 24, 2451-2451 (1983)
Inaba, S.; Rieke, R. D.
Tetrahedron Letters, 26, 155-155 (1985)
Inaba, S.; Matsumoto, H.; Rieke, R. D.
The Journal of Organic Chemistry, 49, 2093-2093 (1984)
Inaba, S.; Rieke, R. D.
Synthesis, 842-842 (1984)

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