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809365

Sigma-Aldrich

Lithium hexafluorophosphate solution

in ethylene carbonate and ethylmethyl carbonate, 2.0 M LiPF6 EC/EMC=50/50(v/v), battery grade

Synonym(s):

2 M LiPF6 [EC/EMC=50/50(v/v)]

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About This Item

Linear Formula:
LiPF6
MDL number:
UNSPSC Code:
12352200
PubChem Substance ID:
NACRES:
NA.23

grade

battery grade

form

liquid

density

1.2966 g/mL

application(s)

battery manufacturing

SMILES string

F[P-](F)(F)(F)(F)F.[Li+]

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

Inchi Key

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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General description

Battery grade: H2O <15 ppm, HF <50 ppm, and APHA <50 ppm.
Lithium hexafluorophosphate solution in ethylene carbonate and ethylmethyl carbonate is a class of electrolytic solution that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.[1][2][3][4]

Application

The solutions of LiPF6 in alkyl carbonates find applications as electrolytes in lithium ion batteries[5][6] and the use of high quality battery grade electrolytes having extremely low water (<15 ppm) and hydrogen fluoride (<50 ppm) contents are critical for achieving high electrochemical performance.

Preparation Note

  • Do not use any glass equipment.
  • Please handle under inert and moisture free environment.

Legal Information

Product of MU Ionic Solutions Corp

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT RE 2 Oral

target_organs

Bone,Teeth, Kidney

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

80.1 °F

flash_point_c

26.7 °C


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Lamb J, et al.
Journal of the Electrochemical Society, 162, A2131-A2131 (2015)
Xu G, et al.
Journal of Material Chemistry A, 3, 4092-4092 (2015)
The Li-ion rechargeable battery: a perspective
Goodenough JB and Park K
Journal of the American Chemical Society, 135(4), 1167-1176 (2013)
Towards greener and more sustainable batteries for electrical energy storage
Larcher D and Tarascon J
Nature Chemistry, 7(1), 19-19 (2015)
Electrodes with high power and high capacity for rechargeable lithium batteries
Kang K, et al.
Science, 311(5763), 977-980 (2006)

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