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Sigma-Aldrich

DTBPF-Pd-G3 GT capsule

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About This Item

Empirical Formula (Hill Notation):
C39H57FeNO3P2PdS
Molecular Weight:
844.15
MDL number:
MFCD28009169
UNSPSC Code:
12352300
PubChem Substance ID:
329768750
NACRES:
NA.22

form

capsule

feature

generation 3

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

functional group

phosphine

InChI

1S/2C13H22P.C12H10N.CH4O3S.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q;;;;;+1/p-1

InChI key

AGXLTHQKOWPGBX-UHFFFAOYSA-M

General description

The product is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has a long life in solutions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio. DTBPF-Pd-G3 is an excellent reagent for cross-coupling reactions.

Application

Convenient dosable form of DTBPF-Pd-G3.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Articles

Buchwald GT Capsules for Cross-Coupling

The advent of the Buchwald portfolio of ligands and complexes for cross-coupling reactions in the past decade has greatly advanced the ease of performing this transformation.

G3 and G4 Buchwald Precatalysts

G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.

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