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Key Documents

805440

Sigma-Aldrich

Reduced graphene oxide

piperazine functionalized

Synonym(s):

rGO-NH, rGO

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About This Item

Linear Formula:
CxOyHz
UNSPSC Code:
12352103
NACRES:
NA.23

form

powder

composition

Carbon, >65 wt. %
Nitrogen, >5 wt. %

conductivity

70.75 S/m (pressed pellets)

SMILES string

CN1CCNCC1.[rGO]

General description

Amount of NH groups:
In order to estimate the amount of NH groups in rGO-NH, a reaction with 4-bromobenzyl chloride was performed and the Br amount was quantified by X-ray fluorescence spectroscopy. The value obtained corresponds to 0.13 mmol/g.

Application

A heterogeneous bifunctional organocatalyst that is able to efficiently promote vintage organic transformations such as Knoevenagel, Michael and Aldol reactions.

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Eduardo Rodrigo et al.
Chemical communications (Cambridge, England), 50(47), 6270-6273 (2014-05-07)
Reduced graphene oxide (rGO) has been used as a support for piperazine to provide a heterogeneous bifunctional organocatalyst (rGO-NH) that is able to efficiently promote vintage organic transformations such as Knoevenagel, Michael and aldol reactions. The obtained results suggest a

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