795151

(S)-t-Bu-Quinox

97%

• Synonym(s): 2-[(4S)-4-(1,1-dimethylethyl)-4,5-dihydro-2-oxazolyl]quinoline
• Empirical Formula (Hill Notation): C₁₆H₁₈N₂O
• CAS Number: 226387-12-8
• Molecular Weight: 254.33
• UNSPSC Code: 12352000
• PubChem Substance ID: 329768469

Properties

• assay: 97%
• form: solid
• reaction suitability: reaction type: Cross Couplings
• mp: 93-98 °C
• SMILES string: CC(C)(C)[C@@H](CO1)N=C1C2=NC3=CC=CC=C3C=C2
• InChI: 1S/C16H18N2O/c1-16(2,3)14-10-19-15(18-14)13-9-8-11-6-4-5-7-12(11)17-13/h4-9,14H,10H2,1-3H3/t14-/m1/s1
• InChI key: ZECIAWBAXVMXKI-CQSZACIVSA-N

Description

Application

Ligand has been shown to influence high enantioselectivity in the asymmetric conjugate addition of boronic acids to enones under palladium catalysis.

Other Notes

Mechanism and Enantioselectivity in Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to ß-Substituted Cyclic Enones: Insights from Computation and Experiment

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable