790869

(S)-3,3′-Dibromo-1,1′-binaphthyl-2,2′-disulfonimide toluene complex

97%

• Empirical Formula (Hill Notation): (C₂₀H₁₁Br₂NO₄S₂)₂ · C₆H₅CH₃
• Molecular Weight: 1198.63
• MDL number: MFCD28016339
• UNSPSC Code: 12352005
• PubChem Substance ID: 329768245
• NACRES: NA.22

Properties

• assay: 97%
• form: solid
• optical activity: [α]22/D +133°, c = 0.5% in chloroform
• reaction suitability: reaction type: Aldol Reaction; reaction type: Allylation; reaction type: Carbonyl/Imine Addition; reaction type: Friedel-Crafts Alkylation
• mp: 303-308 °C (decomposition without melting)
• SMILES string: Cc1ccccc1.Brc2cc3ccccc3c4-c5c(c(Br)cc6ccccc56)S(=O)(=O)NS(=O)(=O)c24.Brc7cc8ccccc8c9-c%10c(c(Br)cc%11ccccc%10%11)S(=O)(=O)NS(=O)(=O)c79
• InChI: 1S/2C20H11Br2NO4S2.C7H8/c2*21-15-9-11-5-1-3-7-13(11)17-18-14-8-4-2-6-12(14)10-16(22)20(18)29(26,27)23-28(24,25)19(15)17;1-7-5-3-2-4-6-7/h2*1-10,23H;2-6H,1H3
• InChI key: WQYRPPIFPJBANM-UHFFFAOYSA-N

Description

Application

Chiral Bronsted acid amenable to modification at the 3 and 3′ positions.

A Powerful Chiral Counteranion Motif for Asymmetric Catalysis

Chiral Sulfonimide as a Brønsted Acid Organocatalyst for Asymmetric Friedel-Crafts Alkylation of Indoles with Imines

Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable