774685

1-Dodecylmagnesium bromide solution

0.5 M in 2-methyltetrahydrofuran

• Synonym(s): Dodecylmagnesium bromide solution
• Linear Formula: CH₃(CH₂)₁₁MgBr
• CAS Number: 15890-72-9
• Molecular Weight: 273.54
• MDL number: MFCD00075165
• UNSPSC Code: 12352103
• PubChem Substance ID: 329767706

Properties

• form: solution
• reaction suitability: reaction type: Grignard Reaction
• concentration: 0.5 M in 2-methyltetrahydrofuran
• density: 0.908 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: CCCCCCCCCCCC[Mg]Br
• InChI: 1S/C12H25.BrH.Mg/c1-3-5-7-9-11-12-10-8-6-4-2;;/h1,3-12H2,2H3;1H;/q;;+1/p-1
• Inchi Key: JSDNASSZWGNUBO-UHFFFAOYSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Packaging

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H250,H261,H302,H314
• pcodes: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 2
• supp_hazards: EUH014,EUH019
• Storage Class: 4.2 - Pyrophoric and self-heating hazardous materials
• wgk_germany: WGK 3
• flash_point_f: 6.8 °F
• flash_point_c: -14 °C