773522

tert-Butylmagnesium chloride solution

• Linear Formula: (CH₃)₃CMgCl
• CAS Number: 677-22-5
• Molecular Weight: 116.87
• Beilstein/REAXYS Number: 3535403
• MDL number: MFCD00000465
• UNSPSC Code: 12352103
• PubChem Substance ID: 329767623
• NACRES: NA.22

Properties

• form: solution
• reaction suitability: reaction type: Grignard Reaction
• greener alternative product characteristics: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• density: 0.878 g/mL at 25 °C
• greener alternative category: , Aligned
• SMILES string: CC(C)(C)[Mg]Cl
• InChI: 1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
• InChI key: ZDRJSYVHDMFHSC-UHFFFAOYSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.

Application

Grignard reagent has been utilized in nucleophilic additions and substitutions; metal-halogen exchanges and Kumada couplings.

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Packaging

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H250,H260,H302,H314
• pcodes: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1
• supp_hazards: EUH019
• Storage Class: 4.2 - Pyrophoric and self-heating hazardous materials
• wgk_germany: WGK 3
• flash_point_f: -22.0 °F
• flash_point_c: -30 °C