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763020

Sigma-Aldrich

[1-(Diphenylphosphino)ethyl]ferrocene

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About This Item

Empirical Formula (Hill Notation):
C24H23FeP
CAS Number:
Molecular Weight:
398.26
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:

form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Coupling Reactions

mp

71-81 °C

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.CC([C]2[CH][CH][CH][CH]2)P(c3ccccc3)c4ccccc4

InChI

1S/C19H18P.C5H5.Fe/c1-16(17-10-8-9-11-17)20(18-12-4-2-5-13-18)19-14-6-3-7-15-19;1-2-4-5-3-1;/h2-16H,1H3;1-5H;

InChI key

WNHZFUIMWGWGNB-UHFFFAOYSA-N

pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Repr. 2 - Skin Irrit. 2

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Ping He et al.
Organic letters, 9(2), 343-346 (2007-01-16)
Anionic four-electron donor-based palladacycle-catalyzed 1,4-additions of arylboronic acids with alpha,beta-unsaturated ketones and 1,2-additions of arylboronic acids with aldehydes and alpha-ketoesters are described. Our study demonstrated that palladacycles were highly efficient, practical catalysts for these addition reactions. The work described here

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