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762393

Sigma-Aldrich

2-(4,4-Dimethyl-4,5-dihydro-2-oxazolyl)pyridine

97%

Synonym(s):

4,4-Dimethyl-2-(pyridin-2-yl)-4,5-dihydrooxazole, pymox-Me2

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About This Item

Empirical Formula (Hill Notation):
C10H12N2O
CAS Number:
109660-12-0
Molecular Weight:
176.22
MDL number:
MFCD05149065
UNSPSC Code:
12161600
PubChem Substance ID:
329766971
NACRES:
NA.22

assay

97%

form

liquid

reaction suitability

reagent type: ligand

refractive index

n20/D 1.533

density

1.050 at 25 °C

storage temp.

2-8°C

SMILES string

CC1(C)COC(=N1)c2ccccn2

InChI

1S/C10H12N2O/c1-10(2)7-13-9(12-10)8-5-3-4-6-11-8/h3-6H,7H2,1-2H3

InChI key

ZANPCQHDEUORJP-UHFFFAOYSA-N

Application

Ligand for Ruthenium catalyzed C-H bond oxidation of arylalkanes.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKBZ2747V
MKBK7089

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Chae S Yi et al.
Organic letters, 11(7), 1567-1569 (2009-02-28)
The cationic complex [(pymox-Me(2))RuCl(2)](+)BF(4)(-) was found to be a highly effective catalyst for the C-H bond oxidation reaction of arylalkanes in water. For example, the treatment of ethylbenzene (1.0 mmol) with t-BuOOH (3.0 mmol) and 1.0 mol % of the

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