Anhydrous crystalline zinc bromide is used for the synthesis of ZnS based composite semiconductor photocatalyst. It is also widely studied to understand the structure-property relationships in zinc bromide and hence predict its different applications. Zinc bromide is a widely used catalyst for stereochemical reactions and is also an important brominating agent.
Chemical & pharmaceutical bulletin, 57(10), 1158-1160 (2009-10-06)
Asymmetric intermolecular hydroacylation between salicylaldehyde (1) and 1,5-hexadiene (2) using a combination of [RhCl(C(8)H(14))(2)](2) (0.10 eq), (S)-BINAP (0.10 eq), and ZnBr(2) (0.20 eq) afforded an enantiomerically enriched hydroacylated product iso-3 of 84% ee, along with an achiral product normal-3.
An oligonucleotide protected with N-(trimethylsilyloxycarbonyl) (Teoc) and P-(trimethylsilylethanol) (Tse) groups was synthesized and deprotected by a single ZnBr2 treatment. Finally it was released from the solid support by cleavage of a disulfide linkage with TCEP. The olgonucleotide was obtained without
Chemical communications (Cambridge, England), (36)(36), 4291-4293 (2008-09-20)
Benzylic and allylic hydrocarbons are selectively converted to the corresponding sulfonamides by a ZnBr2-H2O-catalyzed reaction with PhI=NTs; saturated adamantane is aminosulfonated at the tertiary C-H bond.
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