755591
(Acetonitrile)(2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl)gold(I) hexafluoroantimonate
Synonym(s):
SPhos Au(MeCN)SbF6
About This Item
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form
solid
reaction suitability
core: gold
reagent type: catalyst
impurities
5-10% SPhos-Oxide
mp
>300 °C
SMILES string
[Au+].CC#N.F[Sb-](F)(F)(F)(F)F.COc1cccc(OC)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4
InChI
1S/C26H35O2P.C2H3N.Au.6FH.Sb/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;1-2-3;;;;;;;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6
Inchi Key
DNWMYIZXJFLNDN-UHFFFAOYSA-H
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2
Storage Class
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Related Content
The research of the Echavarren group centers on the development of new reactions based on the use of electrophilic complexes of Au(I), Pt(II), and other transition metals as catalysts and their applications in organic synthesis of complex, biologically active molecules. The Echavarren group is also examining new strategies for the synthesis of polyarenes of interest in material science. In particular, they are interested in the ready construction of C-60 skeletons using reactions catalyzed by Pd(0) and other transition metals.
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