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752983

Aluminum fluoride

Name: Aluminum fluoride
Brand: ALDRICH

anhydrous, ≥99.99% trace metals basis

Synonym(s):

Aluminum trifluoride, Trifluoroaluminum

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About This Item

Linear Formula:

AlF₃

CAS Number:

7784-18-1

Molecular Weight:

83.98

EC Number:

232-051-1

MDL number:

MFCD00003426

UNSPSC Code:

12352302

PubChem Substance ID:

329766330

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grade

anhydrous

assay

≥99.99% trace metals basis

form

solid

mp

1290 °C (lit.)

density

3.1 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

F[Al](F)F

InChI

1S/Al.3FH/h;3*1H/q+3;;;/p-3

InChI key

KLZUFWVZNOTSEM-UHFFFAOYSA-K

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Application

Aluminum Fluoride coatings have been shown to improve the cycling performance of LiCoO₂cathodes[1][2]. AlF₃ is also used in the production of high purity aluminum, fluoroaluminate glasses, and low refractive index thin films[3].

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

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MKBP2017V

MKBK1943V

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Lecoq, A.; et al.

Non-Cryst. Solids, 41, 209-209 (1980)

Sun, Y.-K.; et al.

Electrochemical Communications, 8, 821-821 (2006)

Characterization of AlF3 thin films at 193 nm by thermal evaporation.

Cheng-Chung Lee et al.

Applied optics, 44(34), 7333-7338 (2005-12-16)

Aluminum fluoride (AlF3) was deposited by a resistive heating boat. To obtain a low optical loss and high laser-induced damage threshold (LIDT) at 193 nm, the films were investigated under different substrate temperatures, deposition rates, and annealing after coating. The

AlF.1,4-benzenedicarboxylate: synthesis and absorption properties.

Lumei Liu et al.

Dalton transactions (Cambridge, England : 2003), 39(7), 1722-1725 (2010-05-08)

AlF(bdc), bdc = 1,4-benzenedicarboxylate, a new member of the family of MX(bdc) compounds has been synthesized under solvothermal conditions. It is formed without H(2)bdc in the channels and substantial absorption capacity is observed in its as-synthesized form. AlF(bdc) does not

Density functional theory study on aqueous aluminum-fluoride complexes: exploration of the intrinsic relationship between water-exchange rate constants and structural parameters for monomer aluminum complexes.

Xiaoyan Jin et al.

Environmental science & technology, 45(1), 288-293 (2010-12-08)

Density functional theory (DFT) calculation is carried out to investigate the structures, (19)F and (27)Al NMR chemical shifts of aqueous Al-F complexes and their water-exchange reactions. The following investigations are performed in this paper: (1) the microscopic properties of typical

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