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749206

Sigma-Aldrich

Poly(styrene-block-methyl methacrylate)

average Mn 82,000, block ratio of 2:1

Synonym(s):

PS-block-PMMA, PS-PMMA

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About This Item

CAS Number:
UNSPSC Code:
12162002
NACRES:
NA.23
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form

solid

mol wt

average Mn 25,000 (PMMA)
average Mn 57,000 (polystyrene)
average Mn 82,000

transition temp

Tm 350-355 °C

Mw/Mn

<1.2

InChI

1S/C8H8.C5H8O2/c1-2-8-6-4-3-5-7-8;1-4(2)5(6)7-3/h2-7H,1H2;1H2,2-3H3

InChI key

ADFPJHOAARPYLP-UHFFFAOYSA-N

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General description

52 kDa PS; 52 kDa PMMA; m ~542; n ~250
PS Mn = 52 ± 5 kg/mol
PMMA Mn = 52 ± 5 kg/mol
PDI of the overall block copolymer <1.2
PS molecular weight verified by SEC (taking an aliquot from the reaction mixture) and the PMMA molecular weight by NMR spectroscopy. The overall block copolymer molecular weight distribution would be determined by SEC.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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M H Geiger et al.
Clinical orthopaedics and related research, (382)(382), 258-266 (2001-01-12)
This controlled study compared the strength and porosity of 48 polymethylmethacrylate cement-implant constructs prepared with open bowl versus vacuum mix technique. Forty-eight blast finished stainless steel rods of 13 mm diameter were implanted with centralizers into 17-mm inner diameter tubes
Novel fabrication of 2D and 3D inverted opals and their application.
Jae Ah Lee et al.
Small (Weinheim an der Bergstrasse, Germany), 7(18), 2581-2586 (2011-08-03)
F N K Kwong et al.
The Journal of bone and joint surgery. British volume, 88(1), 120-122 (2005-12-21)
The outcome of a cemented hip arthroplasty is partly dependent on the type of cement which is used. The production of an interface gap between the stem and the cement mantle as a result of shrinkage of the cement, may
S J Breusch et al.
Acta orthopaedica Scandinavica, 72(1), 29-35 (2001-05-01)
In a cadaver study, we prepared 29 paired human cadaver femora using 3 different broaches of identical geometry but different surface characteristics. In one group of 20 pairs, preparation with chipped-toothed broaches was compared to diamond-shaped broaches; in the other
M E Forsythe et al.
Journal of orthopaedic surgery (Hong Kong), 14(1), 38-42 (2006-04-07)
To compare the pharmacokinetic profile of tobramycin in blood, urine, and at the operative site following the use of Simplex-tobramycin bone cement in primary total hip replacement between patients with and without renal dysfunction. Six patients with renal dysfunction underwent

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