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Sigma-Aldrich

Boxed reaction: Buchwald-Hartwig in Lipshutz Surfactant

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About This Item

UNSPSC Code:
12161600
NACRES:
NA.22

form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

This kit contains the reagents, catalyst, and solvent required to perform a Buchwald-Hartwig reaction in TPGS-750-M, a surfactant developed by the Lipshutz group as a greener alternative to organic solvents. This technology allows common metal-catalyzed reactions to be run under aqueous conditions, considerably reducing solvent waste. The components are pre-weighed in the appropriate amounts for a 1 mmol scale reaction.

Please refer to the attached Protocol for details.

Kit Components Also Available Separately

Product No.
Description
SDS
  • 156671Potassium tert-butoxide, reagent grade, ≥98% 180 mgSDS
  • 222380Allylpalladium(II) chloride dimer, 98% 5 mgSDS
  • cBRIDP 8 mg
  • 733857DL-α-Tocopherol methoxypolyethylene glycol succinate solution, 2 wt. % in H2O 1 mLSDS

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Flam. Sol. 2 - Self-heat. 2 - Skin Corr. 1A - Water-react 1

supp_hazards

EUH014

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

Certificates of Analysis (COA)

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