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Sigma-Aldrich

Borane ethylenediamine complex

greener alternative

96%

Synonym(s):

Ethylenediaminebisborane

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About This Item

Empirical Formula (Hill Notation):
C2H14B2N2
CAS Number:
15165-88-5
Molecular Weight:
87.77
UNSPSC Code:
26111700
PubChem Substance ID:
329765205
NACRES:
NA.23

assay

96%

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

114-130 °C (dec.)

greener alternative category

Enabling,

SMILES string

B.B.NCCN

InChI

1S/C2H8N2.2BH3/c3-1-2-4;;/h1-4H2;2*1H3

InChI key

MZYKPEFBHALNHU-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Enantioselective hydride attack of borane-ethylenediamine complex on inclusion compounds of ketones and certain diols and β-cyclodextrin may form optically active alcohols.[1][2]

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL9296
MKBJ3398V

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Ethylenediamine

Application
Rajasree, K. and Devaky, K. S.
Journal of Applied Polymer Science. Applied Polymer Symposium, 82, 593-593 (2001)
Asymmetric Induction by ?-Cyclodextrins in NaBH4 Reduction of Ketones.
Park KK, et al.
J. Incl. Phenom. Mol. Recog. Chem., 27(1), 41-48 (1997)
Ammonia-borane and related compounds as dihydrogen sources.
Anne Staubitz et al.
Chemical reviews, 110(7), 4079-4124 (2010-08-03)
Structure
Ting, H. Y.; Watson, W. H.; Kelly, H. C.
Inorganic Chemistry, 11, 374-374 (1972)
Enantioselective Wittig-Horner reaction in the solid state.
Toda F and Akai H
The Journal of Organic Chemistry, 55(11), 3446-3447 (1990)

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