710334

Bis(2-methoxyphenyl)chlorophosphine

95%

• Empirical Formula (Hill Notation): C₁₄H₁₄ClO₂P
• CAS Number: 263369-88-6
• Molecular Weight: 280.69
• MDL number: MFCD08064037
• UNSPSC Code: 12352112
• PubChem Substance ID: 329762916
• NACRES: NA.22

Properties

• assay: 95%
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp: 109-113 °C
• functional group: phosphine
• SMILES string: COc1ccccc1P(Cl)c2ccccc2OC
• InChI: 1S/C14H14ClO2P/c1-16-11-7-3-5-9-13(11)18(15)14-10-6-4-8-12(14)17-2/h3-10H,1-2H3
• InChI key: PEKLJSZEUFVLKO-UHFFFAOYSA-N

Description

Application

Reactant for:

• Cycloadditions reactions
• Asymmetric hydrogenation and allylic substitution
• Asymmetric hydrogenation of imines and olefins

Reactant for synthesis of:

• Ferrocene-based chiral diphosphine
• Catalysts for C-C cross coupling reactions
• Palladium complexes

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• supp_hazards: EUH014
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable