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Sigma-Aldrich

Small gap fullerene-ethyl nipecotate

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≥95%

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About This Item

Linear Formula:
C60(C8H15NO2)x
UNSPSC Code:
12352103
NACRES:
NA.23

assay

≥95%

form

solid

mol wt

average Mv ~2100

composition

fullerenes, 50%

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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impurities

~5% o-Dichlorobenzene

mp

>300 °C

solubility

organic solvents: soluble
toluene: soluble

greener alternative category

Enabling,

General description

Insoluble small gap fullerenes can be extracted into organic solvents by simple chemical redox process.
Small gap fullerene-ethyl nipecotate are higher order fullerenes with low HOMO-LUMO gaps. These allotropes of carbon are also known as metallofullerenes. They are kinetically unstable and are considered as insoluble small band gap structures. Small gap fullerene-ethyl nipecotate can be extracted into organic solvents by a chemical redox processes.
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Legal Information

Product of TDA Research, Inc. and US Patents 6,517,799 and 6,303,016.

pictograms

Exclamation markEnvironment
GHS07,GHS09

signalword

Warning

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Certificates of Analysis (COA)

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Isolation and properties of small-bandgap fullerenes.
Diener MD and Alford JM
Nature, 393(6686), 668-668 (1998)
Chemical redox recovery of giant, small-gap and other fullerenes
Raebiger, J.W.; Alford, J.M.; Bolskar, R.D.; Diener, M.D.
Carbon, 49, 37-46 (2011)
Small-bandgap endohedral metallofullerenes in high yield and purity.
Stevenson S, et al.
Nature, 401(6748), 55-55 (1999)

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