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704830

Sigma-Aldrich

5-Bromo-2-(tributylstannyl)pyridine

97% (H-NMR)

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About This Item

Empirical Formula (Hill Notation):
C17H30BrNSn
CAS Number:
611168-46-8
Molecular Weight:
447.04
MDL number:
MFCD10699138
UNSPSC Code:
12352103
PubChem Substance ID:
329762483
NACRES:
NA.22

assay

97% (H-NMR)

form

liquid

refractive index

n20/D 1.535

bp

140-145 °C

density

1.317 g/mL at 25 °C

SMILES string

CCCC[Sn](CCCC)(CCCC)c1ccc(Br)cn1

InChI

1S/C5H3BrN.3C4H9.Sn/c6-5-2-1-3-7-4-5;3*1-3-4-2;/h1-2,4H;3*1,3-4H2,2H3;

InChI key

ZQJRPQMEYHJPJK-UHFFFAOYSA-N

Application

5-Bromo-2-(tributylstannyl)pyridine can be used in the synthesis of:
  • 1,10-Phenanthroline based ditopic ligand, which is used to prepare bistable metallic rotaxanes.
  • Donor-acceptor type isomeric platinum(II) complexes exhibiting excellent optoelectronic properties for OLED applications.
  • Pt(II) polymetallayne derived orange phosphorescent polymers applicable in phosphorescent OLEDs (PHOLEDs).

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

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Enhancing the electroluminescence performances of novel platinum (ii) polymetallayne-based phosphorescent polymers through employing functionalized Ir III phosphorescent units and facilitating triplet energy transfer
Huang Z, et al.
Royal Society of Chemistry Advances, 5(16), 12100-12110 (2015)
Achieving NIR emission for donor-acceptor type platinum (II) complexes by adjusting coordination position with isomeric ligands
Zhang Y, et al.
Inorganic Chemistry, 57(22), 14208-14217 (2018)
Synthesis of a novel ditopic ligand incorporating directly bonded 1, 10-phenanthroline and 2, 2': 6', 2 ?-terpyridine units.
Gavi?a P and Tatay S.
Tetrahedron Letters, 47(20), 3471-3473 (2006)

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