697591

(R,R)-ANDEN-Phenyl Trost Ligand

technical grade

• Synonym(s): (+)-(11R,12R)Bis[2′-(diphenylphosphino)benzamido]-9,10-dihydro-9,10-ethanoanthracene, (11R,12R)-N,N′-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)]benzamide
• Empirical Formula (Hill Notation): C₅₄H₄₂N₂O₂P₂
• CAS Number: 152140-65-3
• Molecular Weight: 812.87
• MDL number: MFCD12546007
• UNSPSC Code: 12352002
• PubChem Substance ID: 329761935

Properties

• grade: technical grade
• form: solid
• optical activity: [α]22/D -100°, c = 1 in chloroform
• mp: 125-130 °C
• SMILES string: O=C(N[C@H]1[C@H](NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)[C@H]5c6ccccc6[C@@H]1c7ccccc57)c8ccccc8P(c9ccccc9)c%10ccccc%10
• InChI: 1S/C54H42N2O2P2/c57-53(45-33-17-19-35-47(45)59(37-21-5-1-6-22-37)38-23-7-2-8-24-38)55-51-49-41-29-13-15-31-43(41)50(44-32-16-14-30-42(44)49)52(51)56-54(58)46-34-18-20-36-48(46)60(39-25-9-3-10-26-39)40-27-11-4-12-28-40/h1-36,49-52H,(H,55,57)(H,56,58)/t49-,50+,51-,52-/m1/s1
• InChI key: BEKZNCOFLFMFHP-HRHVFIINSA-N

Description

Application

Catalyst involved in asymmetric allylic alkylations

Asymmetric allylic alkylation ligand.

Legal Information

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only. US Patent 5739396 applies.

Safety Information

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)