686190

Chlorodicarbonyl(1-(isopropylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium(II)

96%

• Synonym(s): Dicarbonylchloro[(1,2,3,4,5-η)-1-[(1-methylethylamino]-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]ruthenium
• Empirical Formula (Hill Notation): C₃₄H₂₈ClNO₂Ru
• CAS Number: 470688-18-7
• Molecular Weight: 619.11
• UNSPSC Code: 12161600
• PubChem Substance ID: 329761029

Properties

• assay: 96%
• form: powder
• reaction suitability: core: ruthenium; reagent type: catalyst
• SMILES string: [Cl-].[Ru+].[C-]#[O+].[C-]#[O+].CC(C)N[C]1[C]([C]([C]([C]1c2ccccc2)c3ccccc3)c4ccccc4)c5ccccc5
• InChI: 1S/C32H28N.2CO.ClH.Ru/c1-23(2)33-32-30(26-19-11-5-12-20-26)28(24-15-7-3-8-16-24)29(25-17-9-4-10-18-25)31(32)27-21-13-6-14-22-27;2*1-2;;/h3-23,33H,1-2H3;;;1H;/q;;;;+1/p-1
• InChI key: BRMXQWNTLPPMGQ-UHFFFAOYSA-M

Description

Application

Catalyst for asymmetric:

• Synthesis of achaetolide
• Transfer hydrogenation and racemization
• Total synthesis of stagonolide-C

Reactant for synthesis of air-stable racemization catalysts

Racemization catalyst for dynamic kinetic resolution of secondary alcohols

Metal catalyst used in conjunction with enzymes for enantioselective transformations via dynamic kinetic resolution.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves