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686050

Sigma-Aldrich

Lithium amide

greener alternative

hydrogen-storage grade

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About This Item

Linear Formula:
LiNH2
CAS Number:
Molecular Weight:
22.96
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

grade

hydrogen-storage grade

assay

95%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

380-400 °C

density

1.178 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

[Li].CN

InChI

1S/Li.H2N/h;1H2/q+1;-1

InChI key

AFRJJFRNGGLMDW-UHFFFAOYSA-N

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General description

Lithium amide (LiNH2) is an amide of an alkali metal with lithium atoms having larger positive charges than hydrogen atoms. It is a moisture-sensitive molecule that converts to LiOH and NH3 on reaction with H2O. It is majorly used in hydrogen storage applications.[1][2][3]
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Analysis Note

Hydrogen content, XRD plots and metal purity data are available upon request.

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B - Water-react 2

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Interaction between lithium amide and lithium hydride.
Chen P
The Journal of Physical Chemistry B, 107(39), 10967-10970 (2003)
A mechanism for non-stoichiometry in the lithium amide/lithium imide hydrogen storage reaction
David WIF, et al.
Journal of the American Chemical Society, 129(6), 1594-1601 (2007)
First-principles study on lithium amide for hydrogen storage
Miwa K, et al.
Physical Review. B, Condensed Matter and Materials Physics, 71(19), 195109-195109 (2005)

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Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

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