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685127

Sigma-Aldrich

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose™ tablets

Loading: 2μmol per tablet

Synonym(s):

ChemDose™, [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II )complex with dichloromethane impregnated tablets, [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1)

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About This Item

Empirical Formula (Hill Notation):
C35H30Cl4FeP2Pd
CAS Number:
95464-05-4
Molecular Weight:
816.64
MDL number:
MFCD00792899
UNSPSC Code:
12352200
PubChem Substance ID:
329760944

form

pellets

matrix

Magnesium aluminometasilicate base material

SMILES string

[Fe].ClCCl.Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h2*1-14H;1H2;2*1H;;/q;;;;;;+2/p-2

InChI key

CWHRHCATIKFSND-UHFFFAOYSA-L

Legal Information

ChemDose is a trademark of Reaxa Ltd.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKBB0826
06403DH
02226TH

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Questions

1–7 of 7 Questions  

  1. Can I use ChemDose® tablets in a microwave or pressure vessel?

    1 answer

    1. Absolutely. Please see the Technical Information for Download section (below) for additional examples of cross-coupling reactions involving the use of microwaves.

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  2. How should I dispose of spent ChemDose® tablets?

    1 answer

    1. They should be treated as solid waste, contaminated with reaction species. The matrix is non-toxic and environmentally benign.

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  3. How should I store ChemDose® tablets?

    1 answer

    1. As with most catalysts and ligands, as a general precaution it is best to store them in a refrigerator and/or under an inert atmosphere to maintain activity. Some catalysts, such as Pd(dppf)Cl2·CH2Cl2, are more robust and can be handled in air without issue. Please refer to the ChemDose® label for specific handling of a given catalyst, ligand, or reagent.

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  4. What is the pH stability of the ChemDose® tablets?

    1 answer

    1. The ChemDose® tablets are mildly basic and will dissolve in the presence of mineral acids.

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  5. Do the ChemDose® tablets disintegrate during the course of the reaction?

    1 answer

    1. They are normally recovered intact, however, they may disintegrate somewhat in aqueous reactions. Any disintegrated tablets can be removed from the reaction via filtration.

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  6. Can I use ChemDose® tablets in any solvent?

    1 answer

    1. Yes, including aqueous solvents.

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  7. What is the Department of Transportation shipping information for this product?

    1 answer

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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