682381

Grubbs Catalyst^® M360

• Synonym(s): Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][3-(2-pyridinyl) propylidene]ruthenium(II), Grubbs Catalyst^® C598, [1,3-Dimesityl-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium(II)
• Empirical Formula (Hill Notation): C₂₉H₃₅Cl₂N₃Ru
• CAS Number: 802912-44-3
• Molecular Weight: 597.58
• UNSPSC Code: 12161600
• PubChem Substance ID: 24885713
• NACRES: NA.22

Properties

• mp: 190.5-199.0 °C
• storage temp.: 2-8°C
• SMILES string: Cc1cc(C)c(N2CCN(C2[Ru](Cl)(Cl)=CCCc3ccccn3)c4c(C)cc(C)cc4C)c(C)c1
• InChI: 1S/C21H27N2.C8H9N.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-2-5-8-6-3-4-7-9-8;;;/h9-13H,7-8H2,1-6H3;1,3-4,6-7H,2,5H2;2*1H;/q;;;;+2/p-2
• InChI key: LCRADYBTPYSTNK-UHFFFAOYSA-L

Description

Application

Metathesis: Ruthenium-Based Metathesis Catalysts

• Catalyst for olefin metathesis reactions

• Latent initiator, but extremely active once initiated, similar to other 2^nd generation catalysts.
• Useful in ROMP applications where longer monomer/catalyst resin handling times are desired.
• Potentially useful in non-ROMP applications as well.
• Enabling metathesis catalyst.

Legal Information

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at www.pmc.umicore.com.

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable