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673269

Sigma-Aldrich

Sodium dimethylphenylsilanolate hydrate

97%

Synonym(s):

Phenyl(dimethyl)silanolate sodium salt

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About This Item

Linear Formula:
(C6H5)Si(ONa)(CH3)2 · xH2O
Molecular Weight:
174.25 (anhydrous basis)
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

assay

97%

form

solid

mp

197-218 °C

SMILES string

[Na+].[H]O[H].C[Si](C)([O-])c1ccccc1

InChI

1S/C8H11OSi.Na.H2O/c1-10(2,9)8-6-4-3-5-7-8;;/h3-7H,1-2H3;;1H2/q-1;+1;

InChI key

GTSOGRDRMFDZQL-UHFFFAOYSA-N

Application

A useful silicon nucleophile for Pd-catalyzed cross-coupling.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)

Articles

Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.

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