Skip to Content
MilliporeSigma
All Photos(1)

Documents

669164

Sigma-Aldrich

(N-Boc-2-pyrrolyl)dimethylsilanol

97%

Synonym(s):

N-Boc-2-(hydroxydimethylsilyl)pyrrole

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
((CH3)3COC(O))(C4H3N)(Si(CH3)2(OH))
CAS Number:
879904-82-2
Molecular Weight:
241.36
MDL number:
MFCD08457657
UNSPSC Code:
12352103
PubChem Substance ID:
24885023
NACRES:
NA.22

assay

97%

form

solid

mp

48-57 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)OC(=O)n1cccc1[Si](C)(C)O

InChI

1S/C11H19NO3Si/c1-11(2,3)15-10(13)12-8-6-7-9(12)16(4,5)14/h6-8,14H,1-5H3

InChI key

RLDVDBYGGISJNL-UHFFFAOYSA-N

Application

(N-Boc-2-pyrrolyl)dimethylsilanol can be used as a substrate:
  • To prepare cross-coupling products by reacting with various aryl iodides.
  • In the synthesis of alkoxyhydrosiloxanes by reacting with alkoxyhydrosilanes.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Organosilicon Chemistry
Denmark SE and Baird JD
Aldrich Chemfiles, 6(5), 1-14 (2006)
A catalyst-and additive-free synthesis of alkoxyhydrosiloxanes from silanols and alkoxyhydrosilanes
Satoh Y, et al.
Chemical Communications (Cambridge, England), 56(59), 8218-8221 (2020)
Palladium-catalyzed cross-coupling reactions of heterocyclic silanolates with substituted aryl iodides and bromides
Denmark SE and Baird JD
Organic Letters, 8(4), 793-795 (2006)
Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)

Articles

Organosilanols

Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service