667242

Chloro(indenyl)bis(triphenylphosphine)ruthenium(II)

may contain ≤1 molar equivalent dichloromethane/acetone

• Linear Formula: C₉H₇ · RuCl · 2(C₁₈H₁₅P)
• CAS Number: 99897-61-7
• Molecular Weight: 776.25
• MDL number: MFCD01073793
• UNSPSC Code: 12352300
• PubChem Substance ID: 24884897

Properties

• form: solid
• reaction suitability: core: ruthenium; reagent type: catalyst
• impurities: may contain ≤1 molar equivalent dichloromethane/acetone
• SMILES string: Cl[Ru].[CH]1[CH][C]2C=CC=C[C]2[CH]1.c3ccc(cc3)P(c4ccccc4)c5ccccc5.c6ccc(cc6)P(c7ccccc7)c8ccccc8
• InChI: 1S/2C18H15P.C9H7.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-5-9-7-3-6-8(9)4-1;;/h2*1-15H;1-7H;1H;/q;;;;+1/p-1
• InChI key: AUSVTIHCDLKYHV-UHFFFAOYSA-M

Description

Application

Catalyst for olefination of carbonyl compounds.[1] Catalyst precursor for living radical polymerization.[2] Catalyst for redox isomerization of propargylic alcohols.[3]

Catalyst for:

• Single-chain folding of polymers
• Domino redox bicycloisomerization
• Selective radical addition with a designed heterobifunctional halide
• Tandem living radical polymerization via in situ monomer transformation with alcohols
• Atom-economical synthesis of nitrogen heterocycles

Reactant for the synthesis of chiral-at-metal ruthenium allenylidene complexes

Safety Information

• pictograms: GHS08,GHS07
• signalword: Warning
• hcodes: H315,H319,H351
• pcodes: P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable