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655201

Sigma-Aldrich

PEDOT:PSS

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high-conductivity grade, 3.0-4.0% aqueous dispersion

Synonym(s):

PEDOT:PSS, Poly(2,3-dihydrothieno-1,4-dioxin)-poly(styrenesulfonate)

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About This Item

MDL number:
UNSPSC Code:
12352103
NACRES:
NA.23

product name

Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), 3.0-4.0% in H2O, high-conductivity grade

grade

high-conductivity grade

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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concentration

3.0-4.0% in H2O

resistance

1500 Ω/sq, 4 point probe measurement of dried coating based on initial 6μm wet thickness.
500 Ω/sq, 4 point probe measurement of dried coating based on initial 18μm wet thickness.

pH

1.5-2.5 (25 °C, dried coatings)

conductivity

>200 S/cm

viscosity

10-30 cP(20 °C)

density

1.011 g/cm3 (dried coatings)

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storage temp.

2-8°C

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General description

Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) is an organic semiconductor prepared by doping cationic poly(3,4-ethylenedioxythiophene) and poly(4-styrenesulfonate) anion. Its high electrical conductivity and good oxidation resistance make it suitable for electromagnetic shielding and noise suppression. PEDOT:PSS based polymeric films have a high transparency throughout the visible light spectrum and even in near IR and near UV regions, with virtually 100% absorption from 900-2000 nm. PEDOT provides the conduction properties and PSS forms a hydrated colloidal solution.
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Application

Electrical conductivity measurements herewith reported were on a film deposited by spin-coating on a clean glass, then dried (130 °C for 15 minutes on a hotplate). The layer thickness was determined by scratching the layer and measuring the profile/height of the scratch by a stylus profilometer. Electrodes for the measurement were by evaporating metal contacts (four-point probes).
PEDOT:PSS is an intrinsically conductive polymer (ICP) that can be coated on various substrates and nanostructures like fullerenes (C60) to form composites with high electrochemical properties for applications like low-cost printed electronics, optoelectronics, and polymeric solar cells. It can be used as a conductive hydrogel with polyethylene glycol-diacrylate (PEG-DA) for potential applications in tissue engineering. PEDOT:PSS also finds use in other organic electronic applications like organic thin film transistors (OTFTs) and dye sensitized solar cells (DSSCs).
Ready-to-use high conductivity coating formulation.
Virtually 100% absorption from 900-2,000 nm. No absorption maximum from 400-800 nm. Conductive polymer blend.

Packaging

Packaged in poly bottles

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

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Fine patterning of glycerol-doped PEDOT: PSS on hydrophobic PVP dielectric with ink jet for source and drain electrode of OTFTs
Lee M, et al.
Organic Electronics, 11(5}, 854-859 (2010)
Dye sensitized solar cells (DSSCs) based on modified iron phthalocyanine nanostructured TiO2 electrode and PEDOT: PSS counter electrode.
Balraju P, et al.
Synthetic Metals, 159(13), 1325-1331 (2009)
Mechanically robust, photopatternable conductive hydrogel composites.
Pal R, et al.
Reactive and Functional Polymers, 120(5), 66-73 (2017)
New Conducting and Semiconducting Polymers for Organic Photovoltaics.
Sapp S and Luebben S
MRS Online Proceedings Library, 1270(4), 261-266 (2010)
EFFECTIVENESS OF ANNEALING TREATMENT AND POLYMER BLENDS ON IV CHARACTERISTSICS OF POLYMER SOLAR CELL.
Rosa E and Shobih S
Reaktor, 14(4), 261-266 (2014)

Articles

In the field of organic printable electronics, such as OLEDs and organic photovoltaics (OPVs), improved organic conducting and semiconducting materials are needed. The progress in two fields is reviewed in this article.

Conducting polymers such as polyaniline, polythiophene and polyfluorenes are now much in the spotlight for their applications in organic electronics and optoelectronics.

Advancements in bioelectronics, incorporating self-healing materials for wearable devices, and measuring bioelectric signals to assess physiological parameters.

Progress in Organic Thermoelectric Materials & Devices including high ZT values of >0.2 at room temperature by p-type (PEDOT:PSS) & n-type (Poly[Kx(Ni-ett)]) materials are discussed.

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