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Key Documents

653268

Sigma-Aldrich

Thulium(II) iodide

anhydrous, powder, ≥99.9%

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About This Item

Linear Formula:
TmI2
CAS Number:
Molecular Weight:
422.74
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

anhydrous

Quality Level

assay

≥99.9%

form

powder

reaction suitability

reagent type: catalyst
core: thulium

impurities

≤1000.0 ppm Trace Rare Earth Analysis

SMILES string

I[Tm]I

InChI

1S/2HI.Tm/h2*1H;/q;;+2/p-2

InChI key

XGGRJQVPUOEAEU-UHFFFAOYSA-L

Application

Promotes the cross-coupling of 2-acetylthiophene or ethyl 2-thiophenecarboxylate with aldehydes and ketones in THF at room temperature.[1]

Features and Benefits

Reducing agent similar to SmI2

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Tetrahedron Letters, 45, 2703-2703 (2004)

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