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649287

Sigma-Aldrich

Poly(2-vinylcarbazole)

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About This Item

Linear Formula:
(C14H11N)n
CAS Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:

form

solid

mol wt

average Mn 1530
average Mw 6400

Mw/Mn

4.2

SMILES string

Cl[H].NC(=N)SCc1ccccc1

InChI

1S/C14H11N/c1-2-10-7-8-12-11-5-3-4-6-13(11)15-14(12)9-10/h2-9,15H,1H2

InChI key

JJEJACZBVVTDIH-UHFFFAOYSA-N

General description

Poly(2-vinylcarbazole) (PVCz) is a conducting polymer that can be used as a hole transporting material in the development of organic electronic devices. It provides a quantum efficiency of ~12% with phosphorescence properties in a variety of mediums, where the triplet level can reach up to 3 eV in the solution media.[1][2]

Application

PVCz can be doped with an electron acceptor to form a photo-induced film, which can further be used in the fabrication of organic light emitting diodes (OLEDs).[1][2]

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Is Poly (vinylcarbazole) a Good Host for Blue Phosphorescent Dopants in PLEDs? Dimer Formation and Their Effects on the Triplet Energy Level of Poly (N-vinylcarbazole) and Poly (N-Ethyl-2-Vinylcarbazole).
Jankus V and Monkman AP
Advances in Functional Materials, 21(17), 3350-3356 (2011)
Direct detection of electron transfer processes in photoconductive poly (N-vinylcarbazole) solid film doped with electron acceptors: Temperature dependence of femtosecond to microsecond dynamics.
Katayama T, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 234(17), 107-114 (2012)
Synthetic Metals, 35-37, 1662-1667 (1993)

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