648337

(2R,4R)-(+)-4,5-Dihydro-4-isopropyl-2-(p-tolyl)-1,2λ⁴,3-oxathiazole 2-oxide

98%

• Empirical Formula (Hill Notation): C₁₂H₁₇NO₂S
• CAS Number: 170900-87-5
• Molecular Weight: 239.33
• UNSPSC Code: 12352005
• PubChem Substance ID: 24883575
• NACRES: NA.22

Properties

• assay: 98%
• form: solid
• optical activity: [α]20/D +85°, c = 1% in chloroform
• mp: 82-86 °C (lit.)
• SMILES string: CC(C)[C@@H]1CO[S@@](=O)(=N1)c2ccc(C)cc2
• InChI: 1S/C12H17NO2S/c1-9(2)12-8-15-16(14,13-12)11-6-4-10(3)5-7-11/h4-7,9,12H,8H2,1-3H3/t12-,16+/m0/s1
• InChI key: QCNBRUOJSNBOIE-BLLLJJGKSA-N

Description

Application

(2R,4R)-(+)-4,5-Dihydro-4-isopropyl-2-(p-tolyl)-1,2λ4,3-oxathiazole 2-oxide can be used as a precursor for the preparation of alkyl- and 2 alkenyl sulfoximines by reacting with corresponding Grignard reagents. These sulfoximines may also be used as asymmetric d³ building blocks.

Safety Information

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)