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561029

Sigma-Aldrich

3,5-Difluorophenylmagnesium bromide solution

0.5 M in THF

Synonym(s):

Bromo(3,5-difluorophenyl)magnesium

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50 ML
$282.14

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50 ML
$282.14

About This Item

Linear Formula:
F2C6H3MgBr
CAS Number:
62351-47-7
Molecular Weight:
217.29
MDL number:
MFCD00672005
UNSPSC Code:
12352103
PubChem Substance ID:
24879909
NACRES:
NA.22

$282.14

List Price$354.00Save 20%
Web-Only Promotion

Available to ship onApril 29, 2025Details

Request a Bulk Order

reaction suitability

reaction type: Grignard Reaction

Quality Level

100

concentration

0.5 M in THF

bp

65 °C

density

0.971 g/mL at 25 °C

functional group

fluoro

storage temp.

2-8°C

SMILES string

Fc1cc(F)cc([Mg]Br)c1

InChI

1S/C6H3F2.BrH.Mg/c7-5-2-1-3-6(8)4-5;;/h2-4H;1H;/q;;+1/p-1

InChI key

CURGXPMIRCWEDB-UHFFFAOYSA-M

Related Categories

Application

3,5-Difluorophenylmagnesium bromide can be used:
  • As a starting material in the synthesis of cis-2-phenyl-1-amino-cyclopentanes as AMPA receptor potentiators.[1]
  • To prepare copper(I) complexes, which are used as luminescent guest molecules in organic light-emitting diodes (OLEDs).[2]
  • As an intermediate in the synthesis of 2-aminoethylbenzofuran H3 receptor antagonists.[3]

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
SHBR8093
SHBP7674
SHBM0367
SHBG6277V
SHBG3313V

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Highly efficient green organic light-emitting diodes containing luminescent tetrahedral copper(i) complexes
Igawa S, et al.
Journal of Material Chemistry C, 1(3), 542-551 (2013)
Design and synthesis of a novel series of 1, 2-disubstituted cyclopentanes as small, potent potentiators of 2-amino-3-(3-hydroxy-5-methyl-isoxazol-4-yl) propanoic acid (AMPA) receptors
Shepherd TA, et al.
Journal of Medicinal Chemistry, 45(10), 2101-2111 (2002)
4-(2-[2-(2 (R)-methylpyrrolidin-1-yl) ethyl] benzofuran-5-yl) benzonitrile and related 2-aminoethylbenzofuran H3 receptor antagonists potently enhance cognition and attention
Cowart M, et al.
Journal of medicinal chemistry, 48(1), 38-55 (2005)

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